منابع مشابه
Thermodynamics of micellization of oppositely charged polymers
– The complexation of oppositely charged colloidal objects is considered in this paper as a thermodynamic micellization process where each kind of object needs the others to micellize. This requirement gives rise to quantitatively different behaviors than the so-called mixed-micellization where each specie can micellize separately. A simple model of the grand potential for micelles is proposed ...
متن کاملElectrostatic interaction of oppositely charged double layers
We determined with anisotropic hypernetted chain theory the effective pressure and counterion excess of two oppositely charged surfaces immersed in an electrolyte solution. These thermodynamic properties are enhanced in surfaces with evenly smeared surface charges with respect to those containing confined mobile charges. For low surface charges and moderate reservoir salt concentration ions are...
متن کاملProgrammable co-assembly of oppositely charged microgels.
Here we report the development of an aqueous, self-assembling system of oppositely charged colloids leading towards particle arrangements with controlled order. The colloidal system consists of two types of particles, each consisting of refractive index matched colloidal core-shell microgel particles, which are either negatively charged or amphoteric. By slowly decreasing the pH of our system b...
متن کاملColloidal gelation of oppositely charged particles†
Colloidal gelation has been extensively studied for the case of purely attractive systems, but little is understood about how colloidal gelation is affected by the presence of repulsive interactions. Here we demonstrate the gelation of a binary system of oppositely charged colloids, in which repulsive interactions compete with attractive interactions. We observe that gelation is controlled by v...
متن کاملCoalescence and Breakup of Oppositely Charged Droplets
The coalescence process of oppositely charged drops for different electrical conductivities of liquids is presented. When the electrical conductivity was relatively low, oppositely charged drops failed to coalesce under sufficiently high electrical fields and capillary ripples were formed on the surfaces of droplets after rebound. For a high electrically conductive liquid, it was found that a c...
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ژورنال
عنوان ژورنال: Europhysics Letters (EPL)
سال: 2003
ISSN: 0295-5075,1286-4854
DOI: 10.1209/epl/i2003-00449-1